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  Global Journal of Physical Chemistry 2012, 3: 1
  Research Article Free Article
 
Correlation of solute transfer into alkane solvents from water and from the gas phase with updated Abraham model equations
  Timothy W. Stephensa, Amanda N. Quaya, Vicky Choua, Matthew Loeraa, Connie Shena, Anastasia Wilsona,
William E. Acree, Jr.a, Michael H. Abrahamb
 
     
a Department of Chemistry, 1155 Union Circle # 305070, University of North Texas, Denton, TX 76203-5017, U.S.A
b Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, U.K

   
  Abstract  
  Literature data regarding partitioning of compounds from the gas phase to alkanes and from water to alkanes have been compiled and analyzed in accord with the Abraham solvation parameter model. Mathematical correlations have been developed for describing the partitioning behavior of organic solutes and gases into hexane, heptane, octane and decane. Derived mathematical expressions were found to predict the available partition coefficient data to within 0.15 log units or better.
     
  Keywords  
  Alkane solvents; Partition coefficients; Gibbs energies of solvation; Activity coefficients  
     
   
   
   
   
     

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