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  Global Journal of Inorganic Chemistry. Volume 2, Issue 3 (2011) pp. 177-187
  Research Article
Series of metal thiocyanates self-assembly induced by 5, 8-Diazoniadispiro [] tetradecane dication
  Fu-Kai Zhao, Xiao-Ling Guo, Zhen-Hua Zhang, Jun-Ming Yue, Yun-Yin Niu  
Department of Chemistry, Zhengzhou University, Zhengzhou 450001, PR China
  Self-assembly of pseudohalogenometalates with DDTD dication (DDTD = 5, 8 -Diazoniadispiro[] tetradecane) were studied. Seven supramolecular complexes were obtained and characterized by X-ray crystallography, elemental analyses and IR spectroscopy: (DDTD)2[Mn(SCN)6] (1), (DDTD)2[Cd(SCN)6] (2), (DDTD)2[Ni(SCN)6]·H2O (3), (DDTD)[Zn(SCN)4] (4), (DDTD)[Hg(SCN)Br3] (5), (DDTD)2[Ag2(SCN)4Br2] (6) and {(DDTD)[Cu2(SCN)4]}n (7). These compounds contained a variety of inorganic framework from mononuclear inorganic adduct to 2D sheet polymer, due to the different coordinated modes of metal centers with pseudohalogen, which accordingly led to the change of the C-H···N(S, Br, I) interactions in the complexes. Additionally, the C(O)-H···N(S, Br, I, O) intermolecular interactions in the complexes extended the discrete (0D) or low-dimensional (1D) entities into high-dimensional frameworks to stabilize supramolecular architectures. Thermal analyses (TG, DTG and DSA) revealed that the decomposition of the complexes mainly proceeded in two stages with the consecutive endothermic course.
  Metal thiocyanate; Tetradecane;Supramolecular; Thermal analyses  

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