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  Global Journal of Inorganic Chemistry. Volume 2, Issue 4 (2011) pp. 265-285
  Review Article
Recent advances in direct synthesis of heterometallic complexes
  Valeriya G. Makhankova  
Department of Inorganic Chemistry, National Taras Shevchenko University, Volodymyrska str. 64, Kyiv 01601, Ukraine
  A self-assembly strategy named "direct synthesis of coordination compounds" (DS) based on the usage of metals or their oxides as the starting materials, was developed into an approach for the preparation of heterometallic complexes. Some of the modifications of DS, in particular, concerning different sources of second metal, such as metal powder, oxide, salt, anionic metallocomplexes or compounds with metal in highest oxidation state, were articulated. The main principles of the formation of heterobimetallic complexes as well as features of their crystal structures are briefly reviewed.
  Heterometallic complexes; Direct Synthesis; Crystal Structure  

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