creating knowledge for future



High Quality


Scholarly Publishing
                CAREER NETWORK  
         
World's one of the largest Research
Career Network
Benefits
  •     Academic & Industry jobs
  •     Project funding
  •     Visiting faculty positions
  •     Visiting scientist positions
  •     Invited talks
  •     and more...  
   
Register FREE  
 
 
 
 
 
  Global Journal of Inorganic Chemistry. Volume 2, Issue 2 (2011) pp. 77-84
  Research Article
 
Synthesis, characterization and luminescent property of a novel cadmium(II) metal-organic framework
  Jian-Guo Lin a,b, Ling Qiu a,*, and Qing-Jin Meng b  
     
a Key Laboratory of Nuclear Medicine, Ministry of Health & Jiangsu Key Laboratory of Molecular Nuclear Medicine, Jiangsu Institute of Nuclear Medicine, Wuxi 214063, PR China
b Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China

   
  Abstract  
  Employing the multidentate ligands 1,2,3,4-tetra-(4-pyridyl)-butane (TPB) and 1,2,4-benzene tricarboxylic acid (H3BTC) as mixed bridges, a novel Cd(II) metal-organic framework was obtained and characterized by single crystal X-ray diffraction, [Cd4(TPB)2(BTC3-)2(HBTC2-)(H2O)2·(H2O)]n (1). The three-dimensional (3-D) framework of complex 1 possesses three topologically nonequivalent nodes synchronously and exhibits an unprecedented topology (445968)2(42536)(42537). And the complex displays good thermal stability and strong photoluminescence in the blue region band. Thus it may serve as a potential candidate of thermally stable blue-light-emitting material.
     
  Keywords  
  Cadmium(II) metal-organic framework; 1,2,3,4-tetra-(4-pyridyl)-butane; 1,2,4-benzene tricarboxylic acid; Thermal stability; Luminescence  
     
   
   
   
   
     

  © 2016 Cognizure