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  Journal of Nanoscience Letters 2012, 2: 17
  Research Article
 
Facile template synthesis of polypyrrole microcontainers based on honeycomb polystyrene/FeCl3 hybrid films
  Ya-Wen Zhonga, Lei Lia, De-Yuan Zhong, Vladimir Svrcekcb  
     
a College of Materials, Xiamen University, Xiamen, 361005, P. R. China
b Research Center for Photovoltaics, National Institute of Advanced Industrial Science and Technology (AIST), Central 2, Umezono 1-1-1, Tsukuba, 305-8568, Japan

   
  Abstract  
  In this article, a facile template synthesis of polypyrrole (PPy) microcontainers based on honeycomb polystyrene/FeCl3 (PS/FeCl3) hybrid films was reported. The templatimg hybrid films were prepared with static breath-figure (BF) technique. PPy microcontainers were formed by the selective oxidative polymerization of pyrrole on the hybrid film cavities, which were decorated with interfacial aggregation of FeCl3 for Pickering emulsion effect during the BF process. Synthesize of other materials, e.g. polyaniline, polythiophene, with similar microstructures by the technique is currently under investigation.
     
  Keywords  
  Microporous films; Breath figure; Microcontainer  
     
   
   
   
   
     

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